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2003 Greenland Tour Geo-Adventure Report:

Experience a virtual tour through the Ilimaussaq Complex written by one of 2003’s Geo-Adventure participants. Lots of great scenery pics, rock pics
and a simply excellent story.

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Article (in HTML) - The Fluorescent Minerals
of the Ilimaussaq Complex,
South Greenland or click on image for a PDF File

Iceberg Arches

Fluorescent Minerals of the Ilimaussaq Complex, Greenland

This is a “glowhound’s” summary of rocks and minerals found within the Ilimaussaq Complex. Every attempt (within a hobbyist’s means) was made to verify the identification of each mineral. Pictures were taken using a Kodak DC4800 and plentiful UV light - all photos are unretouched except for cropping and background cleanup; colors are replicated as closely as possible given the constraints of digital cameras, digital printing and color mixing (as well as human perception of colors). Further research by more qualified individuals will result in much more useful studies; this is only a “hobbyist’s teaser” to the excellent scientific articles yet to be published.

The Ilimaussaq Complex

The Ilimaussaq Complex in Southwestern Greenland is an 8x17km intrusion spanning two fjords - Kangerluarsuk fjord and Tunulliarfik fjord. Located near the city of Narsaq, access to certain parts of the complex (Kvanefjeld and Taseq) can be made by foot, while other areas (Kangerluarsuk and Tunulliarfik) requires travel by boat. It is without a doubt the most mineral-rich area in Greenland. Due to the rapid weathering of the friable (brittle and easily crumbled) syenites most of the mountains have no vegetation (no soil). The gray “rockscape” contrasts sharply with the deep blue fjords and gleaming white icebergs.The 1.2 million year old intrusion consists of three different rock suites. Nepheline-bearing augite syenite first formed a shell along the sides and the roof, next a quartz bearing alkali granite and alkali syenite formed two thin sheets near the top, and finally the biggest part and center of the intrusion was formed by a layered series of under-saturated syenites. These three main rock suites represent three pulses of different kinds of magmas. The rocks close to the roof are the oldest. The most common rocks in these areas are a sodalite-nepheline syenite called naujaite, an arfvedsonite-aegirine bearing nepheline syenite called lujavrite, and a eudialyte-bearing nepheline syenite called kakortokite.


Geological map of the Ilimaussaq Complex
based of a map by Ferguson (1964) and since corrected and improved.

Ilimaussaq hosts the widest variety of minerals in Greenland - more than 200 so far, half of them silicates. The silica content of these minerals is much higher than elsewhere in the world. Numerous pegmatites and hydrothermal veins, streaks and patches are found all over the intrusion, but are most common in the areas of Kangerluarsuk and Kvanefjeld.

There are several key localities within the complex. Some of these areas are small intrusions perhaps only meters wide. Many minerals in these areas are found nowhere else in the world.

Each area within the Ilimaussaq Complex yields distinctly different varieties of the more commonly found minerals. Therefore, a discussion of each variety found in each of the four major areas (Kvanefjeld, Taseq Slopes, Tunulliarfik, and Kangerlussaq) is appropriate.


Kvanefjeld Minerals

Kvanefjeld Mountain (700m) is located at the NW corner of the Ilimaussaq Complex. An old mining road crosses the 15km from Narsaq to the valley between Kvanefjeld and the Taseq Slopes. This road gradually climbs 300 meters and then becomes impassable. It is then a nice hike up to the 500 meter level via an old mine access road to an (abandoned) uranium mine. From this point a “trail” leads to the summit of Kvanefjeld, “rock climbing” the last 200 meters. The difficulty is average and not particularly difficult if you are in reasonable shape. The vertical slope is gradual, and mainly consists of following a well-worn trail, while climbing over large pieces of sodalite and lujavrite.

Atop Kvanefjeld one is greeted with a wonderful view of the valley below, Narsaq in the distance, and the iceberg dotted fjords. It is easy to spend the entire day exploring the relatively flat areas at the top, and digging through the years of tailings that the locals have amassed while searching for gem red tugtupite. The main tugtupite mining area is located a short walk to the west and is littered with snow-white pieces of albite and analcime (many actually are white tugtupite). Most pieces glow bright red under SW UV. Occasionally one will meet a local miner pounding away at a white vein in an effort to pry loose some bright red “tutupit”. In recent years gem tugtupite has become quite scarce. Over the 2003 summer season very few pieces were found, bringing the cabochon industry to a virtual halt.

Tugtupite – The tugtupite from the Kvanefjeld area is the most widely known fluorescent mineral from Ilimaussaq. It is typically a bright gemmy red and is the source for the gem material used in making beautiful tugtupite cabochons. A typical piece of gem tugtupite will be found in an analcime and lujavrite matrix, probably along with aegirine crystals. The natural color ranges from a light pink to a deep cherry red. Under shortwave the red glow is unmistakable. Commonly associated (fluorescent) minerals include chkalovite, beryllite, and sorensenite.

Sorensenite – A single locale mineral, only found within the Ilimaussaq Complex. White to pale pink bladed crystals fluoresce a yellow/white under SW UV (medium intensity). Large aggregates on a lujavrite/analcime matrix have been found in the Kvanefjeld area. Most spectacular are the very rare specimens of tugtupite and sorensenite combined.

Sodalite – The sodalite from the Kvanefjeld area is (to date) unremarkable with only a couple of exceptions. Typically it appears to be of a coarser texture (very few pieces of pure sodalite – usually mixed with aegirine and syenite). The fluorescence is a duller orange than those found in other areas of the complex. A blue sodalite was recently found which, while not impressive as a fluorescent specimen (similar to those from Mt St Hilaire in brightness), the tenebrescense is quite remarkable.

Beryllite – One of the minerals thought to be responsible for the varied unusual fluorescent responses of the Ilimaussaq finds is Beryllite. Most often it is found as a soft, white chalky encrustation on pieces such as tugtupite, fluorescent a medium intensity gray/white. Since beryllium is undetectable by EDS, verifying the presence in various minerals has proven a challenge.
Taseq Slopes

A valley separates the Kvanefjeld area and the Taseq Slopes. The Taseq Slopes are expansive, running the entire width of the middle of the complex. Towards the bottom of the slopes there are large boulders that have eroded from the cliffs above. Climbing up, pockets of sodalite, white veins of albite and analcime, and outcroppings of a myriad of other minerals can be observed. Veins within the lujavrite rocks contain fluorescent minerals like sodalite, ussingite, tugtupite, polylithionite, and others.

Tenebrescent gem quality sodalite is often found on the slopes. Tenebrescense is the “color change” caused by exposure to ultraviolet light (usually shortwave). Both tugtupite and sodalite exhibit this characteristic in varying degrees throughout the complex. One important note of interest: freshly split rocks will often initially show a deep purple color, which quickly fades. While similar to tenebrescense, this is usually a “one-shot” occurrence. It never happens again (unless the mineral happens to be a tenebrescent sodalite or tugtupite). But it is often a good indicator of fluorescence.

There are three areas of interest on the Taseq Slopes: the eastern slopes, middle slopes, and western slopes. Only the western slopes have been extensively surveyed (by H. Sorensen and others in the mid 60’s). This area is noted for the heavy concentrations of beryllium, and produces some fantastic specimens. The middle slopes and eastern slopes both produce great examples of sodalite and tugtupite, along with a myriad of unidentified species.

Taseq Tugtupite – Found both in boulders that have rolled to the bottom and in veins towards the top of the slopes, this variety of tugtupite is quite different from that found on Kvanefjeld. It was first found in the summer of 2002. It consists of a coarse grained pink veining in massive crystals of analcime. Often pieces are associated with aegirine (non FL) and what appears to be a spotty green fluorescent analcime. Many pieces have vugs where micro crystals of tugtupite can be found. Daylight color ranges from a light pink to deep pink, but not yet found in a gemmy red state as on Kvanefjeld. This material is also usually quite phosphorescent.
Sodalite (Glacial Boulders) – The Narsaq Elv (river) cuts the valley between the Taseq Slopes and Kvanefjeld. As expected, this cut is filled with water worn (and glacier worn) boulders. Many of these boulders are beautifully round pieces of sodalite. When split open they reveal a coarse grained sodalite mixed with a bright bluish/white fluorescing analcime (per EDS). The brightness of the blue/white FL (shortwave) could be easily mistaken for scheelite. Interestingly, this type of material has only been found in the eroded boulders – not in the cliffs above. The sodalite is usually deeply tenebrescent.
Tugtupite Crystals – The rarest fluorescent find to date was made during the MinerShop 2002 Greenland “Geo-Adventure”. One of that year’s tour members found a boulder of tugtupite on the eastern slopes. When he cracked it open he found a cavity of wonderfully formed tugtupite crystals – a true rarity! Many pieces have micro crystals but this piece was truly remarkable in size. Although not a gemmy red, the tugtupite deepened in color to an intense pink. A coating of what appears to be a uranyl activated green FL covered many areas on the specimens, along with a yellowish glow – perhaps from another associated (unknown) mineral.
Yellow Sodalite – Sodalite is found throughout the complex (probably as common as calcite is on the dumps in Franklin). The finest specimens are gem quality pieces with deep tenebrescense. In the Taseq area a unique variety has been found which appear yellow under natural lighting, distributed in a white albite/analcime matrix. Upon exposure to shortwave UV the sodalite color deepens to a dark purple – almost black. The resulting contrast of purple against the white matrix offers a striking specimen. Under shortwave these pieces will initially glow a bright orange – only to deepen to a rust color as the tenebrescense sets in. Some, as in the piece shown here. have chkalovite (FL green) and an unknown purple fluorescing (and phosphorescent) mineral associated with them.
Sodalite and Tugtupite Combination – Combination pieces of tugtupite and sodalite are rare and only found in a few areas within the complex. One area on the Taseq Slopes offers up some fantastic specimens. Often these pieces also have what appears to be a blue fluorescing analcime (initial EDS results). Careful examination of many of the spots yielding these minerals will show regions of sodalite at the outside perimeter – perhaps with veins of ussingite and polylithionite. Next will be concentrations of chkalovite and possibly analcime, followed by tugtupite. Some pockets might be only one or two feet across, while others can be huge.
Ussingite

Ussingite is another major mineral found within the complex (of interest to the fluorescent community). It is a fine-grained mineral (similar to quartzite in texture) and ranges in color from white to a deep gem purple. Deeply colored pieces are used for cabochons and can be quite attractive.

The fluorescent properties of ussingite remain a mystery. Many pieces do not fluoresce at all (or very dimly), while others fluoresce orange identically to sodalite. A few fluoresce a brilliant green. Tenebrescent ussingite has not yet been found. Most often ussingite is found associated with chkalovite, polylithionite, sodalite and tugtupite and is a good field indicator of the presence of these other minerals.

Silver Polylithionite

Polylithionite is typically found as greenish mica plates covering feldspars throughout the complex. On the Taseq Slopes a bright silver variety of polylithionite is found with fine-grained layers. This variety is as beautiful in natural light and is a brilliant yellow/white under shortwave. Typically the specimens are massive, reaching one meter in diameter, and often associated with tugtupite (which is also quite phosphorescent).

Pink FL Tugtupite

A very unusual variety of tugtupite can be found on the Taseq Slopes. Unlike those found on Kvanefjeld, it fluoresces a bright pink – not the typical cherry red. The response under longwave is also quite remarkable – a bright orange. The natural color is a deep (almost purple) red. In addition, these specimens are dramatically phosphorescent a bluish white. In many pieces tugtupite crystals are found which are clean and well formed (micros). Also, polylithionite is commonly associated with these specimens.

Tugtupite enclosing Chkalovite

Exceptional specimens of chkalovite (FL blue/green) being replaced by tugtupite have been observed on the Taseq Slopes. These pieces are striking due to the patterns, as well as the very interesting formation. The matrix is analcime and lujavrite; the green FL is unknown but most likely uranyl activated.

Tunulliarfik

The Tunulliarfik Fjord cuts right through the middle of the Ilimaussaq Complex. Traveling by boat from Narsaq the sights are wondrous; the deep blue water of the fjords broken by massive white and blue icebergs contrasts remarkably to the rocky cliffs and sparse vegetation on either side of the fjord. Upon approaching the transition zone into the complex the appearance of the land changes abruptly. There is almost a complete absence of vegetation due to the rapid weathering of the friable syenites – only gray rocks with an occasional white vein high above. Boulders lie at the water’s edge and landslide areas offer up exciting areas to prospect. Gem quality ussingite, massive veins of sodalite, and brilliant assortments of multi-color tugtupite specimens can all be found here.

Ussingite, Sodalite, Chkalovite, Tugtupite and Polylithionite – Ussingite seems closely related to sodalite and may even be mistaken for it. The ussingite from the Tunulliarfik area is possibly the best in the complex. Gem quality pieces are found, usually associated with sodalite, tugtupite and polylithionite - making for a striking 4 or 5 color specimen. One of the mysteries of ussingite is its fluorescence – the response seems to vary from bright orange to bright green to none (or very dim).
“Tugtulite” – Tugtup Agtakorfia is a small area right on the water in the Tunulliarfik Fjord. It is the type locality for tugtupite – discovered in 1962 by Sorensen. All of the pink/red tugtupite has since been mined and all that was left in the vein were some remarkable specimens of sodalite and this presently unknown mineral. This material has three distinct color states under each wavelength - bright peach under SW, bright white under MW, and bright orange under LW. Additionally it is extremely phosphorescent a greenish white - lasting for a very long time. EDS analysis reveals that the peach FL mineral is “not a homogenous phase, but rather a mixture of at least two and likely three different phases.” It appears that the bulk of the material is sodalite but the activating agent could not be detected by EDS. Beryllium is part of the chemical makeup of tugtupite and cannot be detected (easily) with EDS. Further research is being conducted on the makeup of this mineral but for now we have given it the nickname “tugtulite” for a combination of sodalite and tugtupite.
Solid Sodalite – Some of the nicest solid pieces of sodalite have been found in the Tunulliarfik areas. These pieces are simply glowing embers under UV light. They are often quite tenebrescent, and can overwhelm almost any piece placed next to it in a display cabinet. Natural colors range from a pale white to a deep green and most are quite translucent.
Pea-Green Sodalite – An exceptionally bright variety of sodalite comes from a single area within the Tunulliarfik Fjord. This variety is colored a bright “pea-green” under natural light. It is somewhat coarse grained with aegirine distributed throughout. Under longwave the pieces glow as if they were on fire. Interestingly they are not tenebrescent.
Kangerluarsuk

The Kangerluarsuk Fjord forms the southeast boundary of the Ilimaussaq Complex. Like Tunulliarfik, the fjord cuts right through the complex. Steep cliffs rise from each side of the fjord. A large, relatively flat, rock-strewn area is located at the end of the fjord and is one of the three most productive areas in the complex. Significant exploration in the ‘60s revealed large deposits of beryllium, finds of tugtupite and other rare minerals. It was in this area that a find of deeply tenebrescent green sodalite was made in 2000.

A large boulder, the outward appearance unremarkable, was split with a hammer (picture to the left). The sodalite inside was colored a deep and bright purple. After a few minutes the purple faded to a bright green. Once examined under shortwave UV the brightness of the sodalite was amazing, and to add to that, the color change returned! The pieces once again darkened to a deep purple. This find is responsible for the continued exploration of the complex for fluorescent minerals.

Tenebrescent Green Sodalite – Under natural light a greenish colored sodalite interspersed in a lujavrite matrix. Both SW and LW UV cause a brilliant orange fluorescence, and once removed from the SW source the green areas have turned a dark grape purple. After a few minutes exposure to light the purple will fade back to green and the process can be repeated. Most of these pieces also have a bright green “coating” of some uranyl activated (most likely) mineral. Another commonly found mineral in these specimens is Steenstrupine; in those pieces a slight amount of radioactivity may be detected.
Polylithionite - Ilimaussaq is the type locale for this beautifully fluorescent mineral. It is a lithium mica found almost everywhere in the pegmatite dikes and the syenites. Tablets up to two feet have been found sparkling with faint green plates of polylithionite. Under SW they glow a brilliant yellow/white. Polylithionite specimens from Kangerluarsuk are exceptionally well formed, large and bright. Polylithionite grows as veins within other minerals (most often ussingite and tugtupite) and in mica’s typical habit as plates atop the lujavrites and other rocks in the complex.
Combination Sodalite, Tugtupite and Polylithionite

There are reports from material written in the 60’s of a trail of large white boulders running from the base of the cliffs to the water’s edge; the result of a vein of albite/tugtupite from which the surrounding syenites had eroded away. These boulders have since disappeared, but each winter the water and ice seem to “dig up” additional specimens of white material in frost heaves which, when put under UV, rate among the prettiest minerals of the complex.

The sodalite is nicely tenebrescent, and glows a bright orange, while the tugtupite glows a bright cherry red. Fine-grained polylithionite glows a brilliant yellow/white. The blue FL in this picture “escaped” (some lucky Ebay buyer) before it could be identified, and no more specimens like this one have been found.

Tugtupite and Polylithionite

Kangerlussaq yields dramatic specimens of a white variety of tugtupite (appears to be albite under natural light). When associated with small crystals of polylithionite the brightness and depth of the red tugtupite is amazing.

Tugtupite, Sodalite, Polylithionite, and numerous unknowns

Complex and striking mixed specimens are found in frost heaves where an ancient albite vein has broken up over the millennia. These pieces usually consist of an albite and aegirine matrix and seem to have every mineral found in the complex associated with them.

Some varieties of sodalite are a pure white under natural light. In the Kangerlussaq area one type was found that at first seemed innocuous – when a white rock was split it did not appear to be anything special. But after a few minutes of exposure to the sunlight it quickly turned purple! Further investigation showed that this material almost turned black under shortwave UV. This variety of sodalite is extremely tenebrescent – reacting to sunlight, longwave, and shortwave. It is also quite rare as only a couple of kilos were found.

Miscellaneous Associated FL Minerals

There are a wide number of minerals common to many areas within the complex often associated with the major species of fluorescent minerals.. Many are miniatures, small crystals, or massive coatings on the host minerals. Some are easily identifiable from their crystal form, while others are ID’d based on some assumptions and hunches.

Pervasive throughout the complex is a green fluorescence from a very thin coating on the host rock. This has proven impossible to identify using EDS and other methods due to the difficulty in isolating the mineral. The fluorescence indicates a uranyl-activated glow. Until more information can be found this mineral will remain a mystery.

Natrolite

It appears natrolite, and a closely related mineral – tetranatrolite, is responsible for much of the green FL found on many fluorescent minerals from Greenland. Crystal vugs have been found with characteristic (of Natrolite) radiating sprays of acicular needles. Some of these crystals glow a bright green.

Others only glow at the edges, where it appears that the Natrolite crystals are corroding into tetranatrolite(?). In some pieces the natrolite appears to form into a sugary crust (much like albite) and covers large areas of the specimen – providing a pleasing green FL ranging from very bright to quite subdued. Natrolite crystals have also been found which do not fluoresce.

Gaidonnayite

Gaidonnayite is theorthorhombic dimorph of catapleiite. Nicely formed crystal specimens have been found in cavities of nepheline syenites. Crystal Habits include equant, blocky, tabular and wedge-shaped crystals; stacked spherical groups and druses.

It appears that the corroded edges of these crystals glow a bright green under SW only. Reports from MSH indicate response under both SW and LW.

Mysteries

Fluorescent minerals from the Ilimaussaq Complex are slowly being identified as they are found. This process is time consuming and difficult; many specimens contain unknown minerals, with wonderful fluorescence. The purist would first identify these minerals before presenting them to the collecting public – but that takes half the fun out of the hobby. Listed below are pictures, some best guesses, and general observations on some of the (current) mystery finds.

Fluorite and Sodalite (Locale uncertain)
A very rare combination these pieces were believed to be from the Taseq Slopes but the original cache was lost and has not been rediscovered. The fluorite vein runs atop a matrix of gray lujavrite and the sodalite is interspersed throughout. Also a lilac FL mineral is present which has not yet been identified.
Sodalite with ?
Found on the Taseq Slopes this mineral has two veins of a yellowish green FL mineral enclosing coarse grains of sodalite. It is medium bright, white under natural lighting.
Sorensenite and ?
Sorensenite is found throughout the complex but is most notable in the Kvanefjeld area. This specimen was found on the Taseq Slopes and consists of a well-defined crystal in the center – dull yellow/white FL. The mystery is the bright yellow FL from an unknown mineral, perhaps sorensenite in another form?
Tunulliarfik Unknown
A large boulder of sodalite was recovered with this lime green, deeply phosphorescent mineral associated with it. Areas of cherry red tugtupite are sprinkled throughout, and a vein of dimly fluorescent sodalite is enclosed in the lime green FL mineral. Natural color is white.
Yellow Sodalite with Blue FL
Several pieces of deeply tenebrescent sodalite from the Taseq Slopes have been found with a relatively bright blue FL (SW only). The color is similar to fluorite, but there is no response under longwave.
Polylithionite with Purple Fluorescing Mineral
Some nicely formed polylithionite formations from the Kangerlussaq area have a white mineral associated with them which glows a medium bright purple under SW. The feldspar matrix on these pieces also glows the typical dark crimson found with many feldspars.
Summary

The fluorescent minerals of Greenland bring a new and exciting challenge to the hobby. Dozens of new very collectable varieties are being found. As can be seen from this text, many are combinations of just a few rare and exotic minerals – mixed together to create simply awesome specimens. In many cases it has proven extremely difficult to identify some finds. And only the surface has been touched – literally! Collecting in Greenland to date has been focused on surface rocks. Over the coming years veins will be explored and fresh material brought to light that has never seen sunlight. Knowledgeable collectors are making trips to the complex and making new discoveries every year. Who knows what is waiting to be discovered?

Table of FL | Species